Stoichiometric LN Crystal-manufacture,factory,supplier from China

(Total 24 Products for Stoichiometric LN Crystal)
Compared with congruent LN (cLN) crysal, the electro-optic coefficient, nonlinear optical coefficient, periodic polarization reversal voltage and applied photorefractive properties of stoichiometric LN (sLN) crystal are greatly improved. With such excellent physical properties and wide application prospects, sLN crystal has rapidly become a competitive optoelectronic material.sLN crystals are expected to be thermodynamically stable up to their melting temperature at 1170°C, while keeping a largerelectrical resistivity than cLN crystals by one order of magnitude at any temperature.
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Nominally pure stoichiometric LiNbO3 shows lower photorefractive damage resistance than congruent crystal; however, stoichiometric crystals doped with MgO of more than 1.8 mol.
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LN Crystal is a multifunctional material that integrates properties of piezoelectric, ferroelectric, pyroelectric, nonlinear, electro-optical, photoelastic, etc. LiNbO3 has good thermal stability and chemical stability.As one of the most thoroughly characterized nonlinear optical materials, LiNbO3 is suitable for a variety of frequency conversion applications. For example, it is widely used as frequency doublers for wavelength >1 μm and optical parametric oscillators (OPOs) pumped at 1064 nm as well as quasi-phase-matched (QPM) devices.
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LiNbO3 (Lithium Niobate, LN) crystal is a multifunctional material that integrates properties of piezoelectric, ferroelectric, pyroelectric, nonlinear, electro-optical, photoelastic, etc. LiNbO3 has good thermal stability and chemical stability.Among the EO crystals, LN and DKDP are the two primary material that have been practical. DKDP crystals can be easily grown with a high optical homogeneity, which can satisfy the requirement of a large caliber Pockels cell.
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LiNbO3 (Lithium Niobate, LN) crystal is a multifunctional material that integrates properties of piezoelectric, ferroelectric, pyroelectric, nonlinear, electro-optical, photoelastic, etc. LiNbO3 has good thermal stability and chemical stability. Among the EO crystals, LN and DKDP are the two primary material that have been practical. DKDP crystals can be easily grown with a high optical homogeneity, which can satisfy the requirement of a large caliber Pockels cell.
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Pure LiNbO3 (LN) is a good candidate for various optical devices, but has a major disadvantage due to its low threshold optical damage. MgO:LN (congruent compositions) is one of the possible solutions to deal with this problem. MgO doping has played an important role in LN and shown an increased threshold laser beam strength by 100 times. An interesting point is that every physical property of MgO:LN (e.g.
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Lithium  Niobate (LN) crystal has excellent electro-optic, acousto-optic,  piezoelectric and nonlinear properties. More and more attention has been paid on its application in military technology. LN crystal has large nonlinear optical coefficient and can easily achieve non-critical phase matching. As an E-O material, LN crystal has been used as an important optical waveguide material.
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One of the most important drawbacks of popular LiNbO3 crystal is its susceptibility to photorefractive damage (optically induced change of refractive index, usually under exposure with blue or green CW light). The usual way to eliminate this effect is to keep LN crystals at elevated temperatures (400K or more). Another way to prevent photorefractive damage is MgO-doping (usually at levels of around 5 mol% for congruent LN).
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Lithium Niobate (LiNbO3) is widely used  in fiber communication devices as birefringent crystal and used as electro-optic modulator and Q-switch for Nd:YAG, Nd:YLF and Ti:Sapphire lasers. It has good mechanical and physical properties and is ideal for optical polarizing components due to its wide transparency range and low cost. LiNbO3's applications for fiber communication include isolators, circulators, beam displacers, and other polarizing optics. The transverse modulation is mostly employed for LiNbO3 crystal.
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LN crystals are nonhygroscopic and have low absorption coefficient and insert loss. In addition, LN crystal can operate stably in a wide temperature range, which makes them the main EO crystal applied in military laser systems.LN electro-optic Q-switches are widely used in Er:YAG, Ho:YAG, Tm:YAG lasers, and are suitable for low-power Q-switched output, especially in laser ranging. LN Pockels cells can be very compact, and the half-wave voltage can be very low. By doping MgO in LiNbO3, the damage threshold of LN Pockels cells can been increased dramatically.
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LiNbO3 crystal is a low cost photoelectric material with good mechanical and physical properties as well as high optical homogeneity. It has been widely used as frequency doublers for wavelength > 1mm and optical parametric oscillators (OPOs) pumped at 1064nm as well as quasi-phase-matched (QPM) devices. With preferable E-O coefficients, LiNbO3 crystal has become the most commonly used material for Q-switches and phase modulators, waveguide substrate, and surface acoustic wave (SAW) wafers, etc.
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Readily available stock of periodically poled LN (PPLN) crystals can be provided on short lead time, with various specifications of sizes and periods.PPLN SHG crystals are available for pump laser wavelengths 976-2100 nm, generating light 488-1050nm.PPLN OPO crsytals are available for pump sources 515-1064 nm, generating visible and IR CW beams.PPLN DFG crystals are available for various combinations of pump sources, generating wavelengths 2-5.5 um.PPLN SFG crystals are available for various combinations of pump sources, generating wavelengths 500-700 nm.
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The periodic polarized KTP (PPKTP) is a novel nonlinear optical material that can be customized to achieve all of the nonlinear applications required in the entire KTP crystal transmission band, without the phase matching limitations of conventional KTP. Moreover, the effective nonlinear coefficient of PPKTP is about 3 times higher than that of conventional KTP. In the nonlinear application of conventional KTP, the crystal must have a single domain structure, but PPKTP crystal has an artificially induced periodic domain structure.
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LBO (LiB3O5) is a kind of non-linear optical crystal with good ultraviolet transmittance (210-2300 nm), high laser damage threshold and large effective frequency doubling coefficient (about 3 times of KDP crystal). So LBO is commonly used to produce high power second and third harmonic laser light, especially for ultraviolet lasers.LBO has large band gap and transparency region, high non-linear coupling, good chemical and mechanical properties.
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LBO (LiB3O5) is a kind of non-linear optical crystal with good ultraviolet transmittance (210-2300 nm), high laser damage threshold and large effective frequency doubling coefficient (about 3 times of KDP crystal). So LBO is commonly used to produce high power second and third harmonic laser light, especially for ultraviolet lasers.LBO has large band gap and transparency region, high non-linear coupling, good chemical and mechanical properties.
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Diffusion bonded crystal consists of two, three or more parts of crystals with different dopants or same dopant with different doping levels. This material is commonly made by bonding one laser crystal with one or two undoped crystals by precise optical contact and further processing under high temperature.
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Beta-BBO crystal is an important nonlinear optical crystal with combination of unique optical properties, such as broad transmission and phase matching ranges, large nonlinear coefficient, high damage threshold and excellent optical homogeneity. The β-BBO crystal is an efficient material for the second, third and fourth harmonic generation of Nd:YAG lasers, and the best NLO material for the fifth harmonic generation at 213 nm.
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Tm:YAP crystal is one of the most important crystals for LD pumping 2μm laser. The anisotropic structure of Tm:YAP produces anisotropic emission cross section. Tm:YAP crystals with different orientations have different output wavelengths and operating forms for different functions. Compared with the physical and chemical properties of Tm:YAG, the 795nm pump absorption band of Tm:YAP matches the emission wavelength of commonly used high-power AlGaAs diodes better.
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RTP (RbTiOPO4) is an isomorph of KTP crystal. RTP single crystals are grown in WISOPTIC by a slow-cooling flux method. RTP has many advantages e.g. large nonlinear optical coefficient, large E-O coefficient, high damage threshold (about 1.8 times of KTP), high resistivity, high repetition rate, no hygroscopy and no induced piezo-electric effect with electrical signals up to 60 kHz.
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Nd:YLF is an excellent crystal that is very suitable for working in mode-locked mode to obtain short pulse laser. Nd:YLF has very small thermal lens effect (much smaller than YAG crystal), wide fluorescent line, and can generate linear-polarized beam. The relatively small stimulated emission cross section of Nd:YLF makes it suitable for continuous work with low threshold. Nd:YLF crystal has obtained important applications in inertial confinement laser fusion research projects.
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Main SpecificationsDimensionsLength3 ~ 150 mm (± 0.5 mm)Diameter2 ~ 10 mm (+0.00, -0.05 mm)Tm Concentration0.5 ~ 8.0 atm%Orientation[111] (± 1°)Wavefront Distortionλ/4 per inch @ 633 nmBarrel FinishFine ground (400#)End Surface Parallelism ≤ 10”Perpendicularity≤ 5’End Surface Flatnessλ/10 @ 633 nmEnd Surface Quality10-5 [s-d] (MIL-PRF-13830B)Chamfer0.15 ± 0.05 mm @ 45°CoatingAR (R<0.25% @ 2013 nm)
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Tm3+:YLF crystal has a high absorption peak around 792 nm which locates in the diode pumping range, and also has a cross-relaxation process that provides the possibility for each absorbed pump photon to produce to ions at higher laser energy level. Tm3+: YLF laser is very suitable as a pump source for Ho3+:YAG laser. This is due to the good overlap of the emission band of Tm3+:YLF and the absorption band of Ho3+:YAG, and the ability to produce a linearly polarized output.
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Diffusion Bonding Crystal consists of two, three or more parts with different types. They are often used to decrease thermal lens effect, that is conducive to the stability of lasers and high-power laser operation.The Crystals being bonded could be a laser crystal doped with laser-active ions, and its counterparts without dopants (e.g. YAG + Nd :YAG).
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KTA (Potassium Titanyle Arsenate, KTiOAsO4 ) is a nonlinear optical crystal similar to KTP in which atom P is replaced by As. It has good non-linear optical and electro-optical properties, e.g.
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2.2 Fabrication of lithium tantalate crystal with near stoichiometric ratioThe preparation of near-stoichiometric lithium tantalate (NSLT) crystals is difficult. The current methods mainly include: the double crucible method, the flux pulling method, the float zone method and the gas phase exchange equilibrium method. 2.2.1 The double crucible methodIn the double crucible method, the melt material needs to be continuously added to the crucible during the crystal preparation process to keep the melt composition unchanged.
1.2 Near-stoichiometric Lithium Tantalate Crystal Most of the lithium tantalate crystals currently used are grown from melts with the same composition ratio, which is generally called the same composition lithium tantalate (CLT). However, large number of defects affect the physical properties of the CLT crystal, so researchers have conducted study on near-stoichiometric lithium tantalate (NSLT) with less material defects and better physical properties.
2. Fabrication of Lithium Tantalate Crystal2.1 Fabrication of same composition lithium tantalate crystalThe same composition Lithium tantalate (CLT) crystals are often fabricated by mixing high-purity tantalum pentoxide with high-purity lithium carbonate at a stoichiometric ratio of 0.95:1 (molar ratio), and are prepared by the crucible pulling method. The quality of LiTaO3 crystal (www.wisoptic.com) is generally affected by factors such as raw material ratio, pulling speed, seed crystal quality, crucible shape and type.
WISOPTIC is using its newly-set coating machine to do in-house vacuum coatings on crystals and optical components.With our own coating machine and technique, we can provide customers products with excellent quality, e.g. higher surface quality, higher transmittance, and higher LIDT etc.Sorts of dielectric coatings (e.g. AR, HR, PR) are available for crystals (KDP/DKDP, KTP, RTP, BBO, LBO, LN, Nd:YAG, etc) and optical components (laser windows, mirrors, PBS, etc).
3 The main application of lithium tantalate crystal3.2 OscillatorAn oscillator is an energy conversion device that converts DC power into AC power with a certain frequency. This circuit is called an oscillation circuit. The oscillator achieves free oscillation through the mutual conversion between magnetic field energy and electric field energy.Oscillators are divided into RC oscillators, LC oscillators and crystal oscillators. The crystal oscillator has a piezoelectric effect, and the crystal will deform when a voltage is applied to the two poles of the wafer.
3. Experimental EquipmentThe overall device diagram of the frequency doubling experiment is shown in Figure 3(a). The 1064nm continuous light passes through a half-wave plate and is directly focused into the CPPLN crystal by a lens. The generated frequency doubling light passes through a 532nm transparent filter and is received and detected by a power meter. The self-built LD-pumped Nd:YVO4 continuous laser used in the experiment can reach a maximum output power of 22.53W.
2. Theoretical analysis2.1 Temperature robustnessTemperature robustness refers to the stability of the frequency-doubled crystal with respect to temperature. Specifically, when the temperature fluctuates, the power of the frequency-doubled light will not be greatly affected. The influence of temperature on the frequency doubling process mainly comes from the influence on the phase mismatch.
Conclusion Lithium tantalate material has a large pyroelectric coefficient, high Curie temperature, small dielectric loss factor, low heat melt per unit volume, small relative dielectric constant, and stable performance. It is a good ferroelectric and piezoelectric material. It also has extraordinary properties. Because of its linear optical properties, lithium tantalate (LT crystal, www.wisoptic.com) has gradually become a popular material used in communications, electronics and other fields.
2.3 Lithium tantalate single crystal filmAfter the 1980s, thin film preparation technology has developed rapidly. Currently, the commonly used preparation technologies of lithium tantalate single crystal (www.wisoptic.com) thin film mainly include chemical vapor deposition, physical vapor deposition, magnetron sputtering and sol-gel method.The chemical vapor deposition method synthesizes a thin film on a substrate through a chemical reaction and accurately controls the chemical composition of the product. It has the characteristics of low stress and good quality.
04 Theoretical study of thermal properties As can be seen from Figure 5 (a), when the BBO crystal (www.wisoptic.com) matching temperature is 60 ℃, as the 266 nm deep ultraviolet laser power gradually increases from 0.32 W to 1.24 W, 2.09 W and 2.25 W, the fitted nonlinear absorption coefficient βNLA also increases continuously, from 0 to 0.079, 0.128, and 0.189 cm/GW, respectively.
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