LN Crystal is a multifunctional material that integrates properties of piezoelectric, ferroelectric, pyroelectric, nonlinear, electro-optical, photoelastic, etc. LiNbO3 has good thermal stability and chemical stability.As one of the most thoroughly characterized nonlinear optical materials, LiNbO3 is suitable for a variety of frequency conversion applications. For example, it is widely used as frequency doublers for wavelength >1 μm and optical parametric oscillators (OPOs) pumped at 1064 nm as well as quasi-phase-matched (QPM) devices.
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Compared with congruent LN (cLN) crysal, the electro-optic
coefficient, nonlinear optical coefficient, periodic polarization
reversal voltage and applied photorefractive properties of
stoichiometric LN (sLN) crystal are greatly improved. With such excellent
physical properties and wide application prospects, sLN crystal has rapidly become a competitive optoelectronic
material.sLN crystals are expected to be thermodynamically stable up to their melting temperature at 1170°C, while keeping a largerelectrical resistivity than cLN crystals by one order of magnitude at any temperature.
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LiNbO3 (Lithium Niobate, LN) crystal is a multifunctional material that integrates properties of piezoelectric, ferroelectric, pyroelectric, nonlinear, electro-optical, photoelastic, etc. LiNbO3 has good thermal stability and chemical stability.Among the EO crystals, LN and DKDP are the two primary material that have been practical. DKDP crystals can be easily grown with a high optical homogeneity, which can satisfy the requirement of a large caliber Pockels cell.
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LiNbO3 (Lithium Niobate, LN) crystal is a multifunctional material that integrates properties of piezoelectric, ferroelectric, pyroelectric, nonlinear, electro-optical, photoelastic, etc. LiNbO3 has good thermal stability and chemical stability. Among the EO crystals, LN and DKDP are the two primary material that have been practical. DKDP crystals can be easily grown with a high optical homogeneity, which can satisfy the requirement of a large caliber Pockels cell.
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Pure LiNbO3 (LN) is a good candidate for various optical devices, but
has a major disadvantage due to its low threshold optical damage. MgO:LN (congruent
compositions) is one of the possible solutions to deal with this
problem. MgO doping has played an important role in LN and shown an
increased threshold laser beam strength by 100 times. An interesting
point is that every physical property of MgO:LN (e.g.
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Lithium Niobate (LN) crystal has excellent electro-optic, acousto-optic, piezoelectric and nonlinear properties. More and more attention has been paid on its application in military technology. LN crystal has large nonlinear optical coefficient and can easily achieve non-critical phase matching. As an E-O material, LN crystal has been used as an important optical waveguide material.
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One of the most important drawbacks of popular LiNbO3 crystal is its
susceptibility to photorefractive damage (optically induced change of
refractive index, usually under exposure with blue or green CW light).
The usual way to eliminate this effect is to keep LN crystals at
elevated temperatures (400K or more). Another way to prevent
photorefractive damage is MgO-doping (usually at levels of around 5 mol%
for congruent LN).
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Lithium
Niobate (LiNbO3) is widely used in fiber communication devices as birefringent
crystal and used as electro-optic modulator and Q-switch
for Nd:YAG, Nd:YLF and Ti:Sapphire lasers. It has good mechanical and physical properties and is ideal for optical
polarizing components due to its wide transparency range and low cost. LiNbO3's applications for fiber communication include isolators, circulators, beam displacers, and other polarizing
optics. The transverse modulation is mostly employed for
LiNbO3 crystal.
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LN crystals are nonhygroscopic and have low absorption coefficient and insert loss. In addition, LN crystal can operate stably in a wide temperature range, which makes them the main EO crystal applied in military laser systems.LN electro-optic Q-switches are widely
used in Er:YAG, Ho:YAG, Tm:YAG lasers, and are suitable for low-power
Q-switched output, especially in laser ranging. LN Pockels cells can be very compact, and the half-wave voltage can be very low. By doping MgO in LiNbO3, the damage threshold of LN Pockels cells can been increased dramatically.
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LiNbO3 crystal is a low cost photoelectric material with good mechanical
and physical properties as well as high optical homogeneity. It has
been widely used as frequency doublers for wavelength > 1mm and
optical parametric oscillators (OPOs) pumped at 1064nm as well as
quasi-phase-matched (QPM) devices. With preferable E-O coefficients,
LiNbO3 crystal has become the most commonly used material for Q-switches
and phase modulators, waveguide substrate, and surface acoustic wave
(SAW) wafers, etc.
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Readily available stock of periodically poled LN (PPLN) crystals can be provided
on short lead time, with various specifications of sizes and periods.PPLN SHG crystals are available for pump
laser wavelengths 976-2100 nm, generating light 488-1050nm.PPLN OPO crsytals are available for pump sources 515-1064 nm, generating visible
and IR CW beams.PPLN DFG crystals are available for various combinations of pump sources, generating wavelengths 2-5.5 um.PPLN SFG crystals are available for various combinations of pump
sources, generating wavelengths 500-700 nm.
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The periodic polarized KTP (PPKTP) is a novel nonlinear optical material that can be customized to achieve all of the nonlinear applications required in the entire KTP crystal transmission band, without the phase matching limitations of conventional KTP. Moreover, the effective nonlinear coefficient of PPKTP is about 3 times higher than that of conventional KTP. In the nonlinear application of conventional KTP, the crystal must have a single domain structure, but PPKTP crystal has an artificially induced periodic domain structure.
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Nd:YVO4 (Neodymium-doped Yttrium Vanadate) is the most efficient laser crystal for diode-pumped solid-state lasers. Its good physical, optical and mechanical properties make Nd:YVO4 an excellent crystal for high power, stable and cost-effective diode-pumped solid-state lasers, especially for lasers with low or middle power density. Nd:YVO4 is
a good choice for highly polarized output at 1342 nm, as the emission
line is much stronger than those of its alternatives.
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RTP (RbTiOPO4) is an isomorph of KTP crystal. RTP single crystals are grown in WISOPTIC by a slow-cooling flux method. RTP has many advantages e.g. large nonlinear optical coefficient, large E-O coefficient, high damage threshold (about 1.8 times of KTP), high resistivity, high repetition rate, no hygroscopy and no induced piezo-electric effect with electrical signals up to 60 kHz.
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Gray Track Resistant (GTR) KTP crystals developed by hydrothermal method overcomes the common phenomenon of
electrochromism of the flux-grown KTP, thus has many advantages such as
high electrical resistivity, low insertion loss, low half-wave voltage,
high laser damage threshold, and wide transmission band. So it's very suitable for high power density
applications, where regular flux-grown KTP crystals will suffer from
gray track damage.GTR-KTP crystal has gray track resistance sufficiently greater than
typical flux-grown KTP.
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Tm3+:YLF crystal has a high absorption peak around 792 nm which locates in the diode pumping range, and also has a cross-relaxation process that provides the possibility for each absorbed pump photon to produce to ions at higher laser energy level. Tm3+: YLF laser is very suitable as a pump source for Ho3+:YAG laser. This is due to the good overlap of the emission band of Tm3+:YLF and the absorption band of Ho3+:YAG, and the ability to produce a linearly polarized output.
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Tm:YAP crystal is one of the most important crystals for LD pumping 2μm laser. The anisotropic structure of Tm:YAP produces anisotropic emission cross section. Tm:YAP crystals with different orientations have different output wavelengths and operating forms for different functions. Compared with the physical and chemical properties of Tm:YAG, the 795nm pump absorption band of Tm:YAP matches the emission wavelength of commonly used high-power AlGaAs diodes better.
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Diffusion bonded crystal consists of two, three or more parts of crystals with different dopants or same dopant with different doping levels. This material is commonly made by bonding one laser crystal with one or two undoped crystals by precise optical contact and further processing under high temperature.
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Beta-Barium Borate (β-BBO) is an excellent nonlinear crystal with combination of a number of unique features: wide transparency region, broad phase-matching range, large nonlinear coefficient, high damage threshold, and excellent optical homogeneity. Therefore, β-BBO provides an attractive solution for various nonlinear optical applications such as OPA, OPCPA, OPO etc.β-BBO also has advantages of large thermal acceptance bandwidth, high damage threshold and small absorption, thus is very suitable for frequency conversion of high peak or average power laser radiation, e.g.
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LBO (LiB3O5) is a kind of non-linear optical crystal with good ultraviolet transmittance (210-2300 nm), high laser damage threshold and large effective frequency doubling coefficient (about 3 times of KDP crystal). So LBO is commonly used to produce high power second and third harmonic laser light, especially for ultraviolet lasers.LBO has large band gap and transparency region, high non-linear coupling, good chemical and mechanical properties.
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Diffusion
Bonding Crystal consists of two, three or more parts
with different types. They are often used to decrease
thermal lens effect, that is conducive to the stability of lasers and
high-power laser operation.The Crystals being bonded could be a laser crystal doped
with laser-active ions, and its counterparts without dopants (e.g. YAG +
Nd :YAG).
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Barium Borate exists in three major crystalline forms: alpha, beta, and
gamma. The low-temperature beta phase converts into the alpha phase upon
heating to 925 °C. β-BBO differs from α-BBO by the
positions of the barium ions within the crystal. Both phases are
birefringent, however α-BBO has centric symmetry and thus
does not has the same nonlinear properties as β-BBO.α-BBO is a negative uniaxial crystal with a large birefringence over the broad transparent range from 189 nm to 3500 nm.
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LBO (LiB3O5) is a kind of non-linear optical crystal with good ultraviolet transmittance (210-2300 nm), high laser damage threshold and large effective frequency doubling coefficient (about 3 times of KDP crystal). So LBO is commonly used to produce high power second and third harmonic laser light, especially for ultraviolet lasers.LBO has large band gap and transparency region, high non-linear coupling, good chemical and mechanical properties.
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High
temperature phase BBO (alpha-BBO, a-BBO) is a negative uniaxial crystal
with a large birefringence over the broad transparent range from 189 nm
to 3500 nm. The physical, chemical, thermal, and optical properties of
alpha-BBO crystal are similar to those of the low temperature phase beta-BBO crystal.
However, there is no second order nonlinear effect in alpha-BBO crystal
due to the centrosymmetry in its crystal structure and thus it has no
use for second order nonlinear optical processes.
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