High temperature phase of α-BBO Crystal (BaB2O4)
is one of the excellent birefringent crystals. It is characterized by
large birefringent coefficient and wide transmission window ranged from
189nm to 3500nm. Due to its high chemical stability and medium hardness,
α-BBO is fabricated easily into many kinds of optical components.The
physical, chemical, thermal and optical properties of α-BBO are similar
to those of β-BBO.
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Barium Borate exists in three major crystalline forms: alpha, beta, and
gamma. The low-temperature beta phase converts into the alpha phase upon
heating to 925 °C. β-BBO differs from α-BBO by the
positions of the barium ions within the crystal. Both phases are
birefringent, however α-BBO has centric symmetry and thus
does not has the same nonlinear properties as β-BBO.α-BBO is a negative uniaxial crystal with a large birefringence over the broad transparent range from 189 nm to 3500 nm.
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High
temperature phase BBO (alpha-BBO, a-BBO) is a negative uniaxial crystal
with a large birefringence over the broad transparent range from 189 nm
to 3500 nm. The physical, chemical, thermal, and optical properties of
alpha-BBO crystal are similar to those of the low temperature phase beta-BBO crystal.
However, there is no second order nonlinear effect in alpha-BBO crystal
due to the centrosymmetry in its crystal structure and thus it has no
use for second order nonlinear optical processes.
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Beta-BBO crystal is an important nonlinear optical crystal
with combination of unique optical properties, such as broad transmission and
phase matching ranges, large nonlinear coefficient, high damage
threshold and excellent optical homogeneity. The β-BBO crystal is an efficient material for the second, third and fourth
harmonic generation of Nd:YAG lasers, and the best NLO material for the
fifth harmonic generation at 213 nm.
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BBO(Beta-Barium Borate, β-BaB2O4)based Pockels cells operate from approximately 0.2 - 1.65 µm and are not subject to tracking degradation. BBO exhibits low piezoelectric response, good thermal stability, and low absorption. Due to the low piezoelectric coupling coefficients of BBO, BBO Pockels cells function at repetition rates of hundreds of kilohertz.
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Beta-Barium Borate (β-BBO) is an excellent nonlinear crystal with combination of a number of unique features: wide transparency region, broad phase-matching range, large nonlinear coefficient, high damage threshold, and excellent optical homogeneity. Therefore, β-BBO provides an attractive solution for various nonlinear optical applications such as OPA, OPCPA, OPO etc.β-BBO also has advantages of large thermal acceptance bandwidth, high damage threshold and small absorption, thus is very suitable for frequency conversion of high peak or average power laser radiation, e.g.
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Beta-Barium Borate (β-BBO) is an excellent nonlinear crystal with combination of a number of unique features: wide transparency region, broad phase-matching range, large nonlinear coefficient, high damage threshold, and excellent optical homogeneity. Therefore, β-BBO provides an attractive solution for various nonlinear optical applications such as OPA, OPCPA, OPO etc. β-BBO also has advantages of large thermal acceptance bandwidth, high damage threshold and small absorption, thus is very suitable for frequency conversion of high peak or average power laser radiation, e.g.
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BBO(Beta-Barium Borate, β-BaB2O4)based Pockels cells operate from approximately 0.2 - 1.65 µm and are not subject to tracking degradation. BBO exhibits low piezoelectric response, good thermal stability, and low absorption. Low
piezoelectric ringing makes this Pockels cell attractive for the control
of high-power and high-pulse repetition rate (hundreds of kilohertz, up to 1MHz) lasers.
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LBO (LiB3O5) is an excellent non-linear crystal of Borate-family following BBO. LBO has advantages of good ultraviolet transmittance (210-2300 nm), high laser damage threshold and large effective frequency doubling coefficient (about 3 times of KDP crystal). Therefore LBO is commonly used to produce high power second and third harmonic laser light, especially for ultraviolet lasers.LBO has large band gap and transparency region, high non-linear coupling, good chemical and mechanical properties.
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The periodic polarized KTP (PPKTP) is a novel nonlinear optical material that can be customized to achieve all of the nonlinear applications required in the entire KTP crystal transmission band, without the phase matching limitations of conventional KTP. Moreover, the effective nonlinear coefficient of PPKTP is about 3 times higher than that of conventional KTP. In the nonlinear application of conventional KTP, the crystal must have a single domain structure, but PPKTP crystal has an artificially induced periodic domain structure.
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Diffusion bonded crystal consists of two, three or more parts of crystals with different dopants or same dopant with different doping levels. This material is commonly made by bonding one laser crystal with one or two undoped crystals by precise optical contact and further processing under high temperature.
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LBO (LiB3O5) is a kind of non-linear optical crystal with good ultraviolet transmittance (210-2300 nm), high laser damage threshold and large effective frequency doubling coefficient (about 3 times of KDP crystal). So LBO is commonly used to produce high power second and third harmonic laser light, especially for ultraviolet lasers.LBO has large band gap and transparency region, high non-linear coupling, good chemical and mechanical properties.
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KTA (Potassium Titanyle Arsenate, KTiOAsO4 ) is a nonlinear optical crystal similar to KTP in which atom P is replaced by As. It has good non-linear optical and electro-optical properties, e.g.
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KTA (Potassium Titanyle Arsenate, KTiOAsO4 ) is a nonlinear optical crystal similar to KTP in which atom P is replaced by As. It has good non-linear optical and electro-optical properties, e.g.
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Tm:YAP crystal is one of the most important crystals for LD pumping 2μm laser. The anisotropic structure of Tm:YAP produces anisotropic emission cross section. Tm:YAP crystals with different orientations have different output wavelengths and operating forms for different functions. Compared with the physical and chemical properties of Tm:YAG, the 795nm pump absorption band of Tm:YAP matches the emission wavelength of commonly used high-power AlGaAs diodes better.
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LBO (LiB3O5) is a kind of non-linear optical crystal with good ultraviolet transmittance (210-2300 nm), high laser damage threshold and large effective frequency doubling coefficient (about 3 times of KDP crystal). So LBO is commonly used to produce high power second and third harmonic laser light, especially for ultraviolet lasers.LBO has large band gap and transparency region, high non-linear coupling, good chemical and mechanical properties.
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Nd:YAG (Neodimium Doped Yttrium Aluminum Garnet) has been and continue to be the most widely used laser crystal for solid-state lasers.
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Nd:YLF is an excellent crystal that is very suitable for working in mode-locked mode to obtain short pulse laser. Nd:YLF has very small thermal lens effect (much smaller than YAG crystal), wide fluorescent line, and can generate linear-polarized beam. The relatively small stimulated emission cross section of Nd:YLF makes it suitable for continuous work with low threshold. Nd:YLF crystal has obtained important applications in inertial confinement laser fusion research projects.
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RTP (RbTiOPO4) is an isomorph of KTP crystal. RTP has many advantages e.g. large nonlinear optical coefficient, large E-O coefficient, high damage threshold (about 1.8 times of KTP), high resistivity, high repetition rate, no hygroscopy and no induced piezo-electric effect with electrical signals up to 60 kHz. The transmission range of RTP is 350 nm to 4500 nm.RTP crystal is widely used in laser Q-switching system with high frequency repetition, high power and narrow pulse width.
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Lithium
Niobate (LiNbO3) is widely used in fiber communication devices as birefringent
crystal and used as electro-optic modulator and Q-switch
for Nd:YAG, Nd:YLF and Ti:Sapphire lasers. It has good mechanical and physical properties and is ideal for optical
polarizing components due to its wide transparency range and low cost. LiNbO3's applications for fiber communication include isolators, circulators, beam displacers, and other polarizing
optics. The transverse modulation is mostly employed for
LiNbO3 crystal.
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RTP (RbTiOPO4) is an isomorph of KTP crystal. RTP single crystals are grown in WISOPTIC by a slow-cooling flux method. RTP has many advantages e.g. large nonlinear optical coefficient, large E-O coefficient, high damage threshold (about 1.8 times of KTP), high resistivity, high repetition rate, no hygroscopy and no induced piezo-electric effect with electrical signals up to 60 kHz.
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Tm3+:YLF crystal has a high absorption peak around 792 nm which locates in the diode pumping range, and also has a cross-relaxation process that provides the possibility for each absorbed pump photon to produce to ions at higher laser energy level. Tm3+: YLF laser is very suitable as a pump source for Ho3+:YAG laser. This is due to the good overlap of the emission band of Tm3+:YLF and the absorption band of Ho3+:YAG, and the ability to produce a linearly polarized output.
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Lithium Niobate (LN) crystal has excellent electro-optic, acousto-optic, piezoelectric and nonlinear properties. More and more attention has been paid on its application in military technology. LN crystal has large nonlinear optical coefficient and can easily achieve non-critical phase matching. As an E-O material, LN crystal has been used as an important optical waveguide material.
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Nd: YLF (Nd:LiYF4) is a laser
material that acts as an alternative to Nd:YAG. It is very suitable for working in mode-locked state to make pulse lasers at wavelength 1053nm, 1047nm, 1313nm, 1324nm and 1370 nm. Nd:YLF has very small thermal lens effect (much smaller than YAG crystal), wide fluorescent line, and can generate linear-polarized beam. The relatively small stimulated emission cross section of Nd:YLF makes it suitable for continuous work with low threshold.
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